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Whilst reading the BBC News I happened to stray upon an article about sea silk which is much rarer than normal silk. It is made from the saliva of a large clam...
http://www.bbc.co.uk/news/magazine-33691781
http://www.bbc.co.uk/news/magazine-33691781
Silk is usually made from the cocoons spun by silkworms - but there is another, much rarer, cloth known as sea silk or byssus, which comes from a clam. Chiara Vigo is thought to be the only person left who can harvest it, spin it and make it shine like gold.
<snip>
The raw material comes from the glistening aquamarine waters that surround the island. Every spring Vigo goes diving to cut the solidified saliva of a large clam, known in Latin as Pinna Nobilis.
She does it early in the morning, to avoid attracting too much attention, and is accompanied by members of the Italian coastguard - this is a protected species. It takes 300 or 400 dives to gather 200g of material.